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. Author manuscript; available in PMC: 2014 Nov 13.
Published in final edited form as: J Am Chem Soc. 2013 Nov 4;135(45):10.1021/ja408073m. doi: 10.1021/ja408073m

Scheme 3.

Scheme 3

The singly occupied orbitals during H-abstraction in: (a) a normal HAT reaction, PhCH2• + PhCH3 → PhCH3 + PhCH2•, and (b) PCET reaction, PhO• + PhOH → PhOH + PhO•