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. Author manuscript; available in PMC: 2014 Nov 20.
Published in final edited form as: J Am Chem Soc. 2013 Nov 6;135(46):10.1021/ja409510d. doi: 10.1021/ja409510d

Figure 8.

Figure 8

Calculated ZFS tensor orientation and intensity for the MnIVFeIII cofactor. Initial ZFS orientation is shown with blue dotted arrows, where x and y orientations rotate to red arrows due to the antisymmetric ZFS arising from hetero-bimetallic center.