| C1—N1 | 1.154 (8) | C5—H5 | 0.9300 |
| C1—C2 | 1.434 (8) | C6—C7 | 1.373 (7) |
| C2—C3 | 1.338 (8) | C6—Br1 | 1.884 (6) |
| C2—H2 | 0.9300 | C7—C8 | 1.506 (8) |
| C3—C4 | 1.452 (8) | C7—S1 | 1.717 (5) |
| C3—H3 | 0.9300 | C8—H8A | 0.9600 |
| C4—C5 | 1.356 (8) | C8—H8B | 0.9600 |
| C4—S1 | 1.737 (5) | C8—H8C | 0.9600 |
| C5—C6 | 1.412 (8) | ||
| N1—C1—C2 | 175.6 (7) | C7—C6—C5 | 114.5 (5) |
| C3—C2—C1 | 120.3 (5) | C7—C6—Br1 | 122.3 (4) |
| C3—C2—H2 | 119.8 | C5—C6—Br1 | 123.3 (4) |
| C1—C2—H2 | 119.8 | C6—C7—C8 | 128.9 (5) |
| C2—C3—C4 | 123.9 (5) | C6—C7—S1 | 109.5 (4) |
| C2—C3—H3 | 118.0 | C8—C7—S1 | 121.6 (4) |
| C4—C3—H3 | 118.0 | C7—C8—H8A | 109.5 |
| C5—C4—C3 | 127.1 (5) | C7—C8—H8B | 109.5 |
| C5—C4—S1 | 110.6 (4) | H8A—C8—H8B | 109.5 |
| C3—C4—S1 | 122.3 (4) | C7—C8—H8C | 109.5 |
| C4—C5—C6 | 112.6 (5) | H8A—C8—H8C | 109.5 |
| C4—C5—H5 | 123.7 | H8B—C8—H8C | 109.5 |
| C6—C5—H5 | 123.7 | C7—S1—C4 | 92.8 (3) |