Table 2.

Redox Potentials of Complexes 1A–D and 1F.^a

complex	solvent	Redox Potentials (mV vs Fc+/0) b
1A	CH2Cl2	E1/2 (ΔE) = −290 (110); Ep,a = +740 mV
1B	CH2Cl2	E1/2 (ΔE) = −110 (140); Ep,a = +1050 mV
1C	CH2Cl2	E1/2 (ΔE) = −30 (150)
1D	THF	Ep,a = −50, +370, and +780 mV
1F	THF	Ep,a = −100, +580, and +850mV

^aConditions: Solutions contained 100 mM (NBu₄)PF₆; scan rate of 100 mV s⁻¹ at room temperature.

^bE_1/2 and ΔE values are provided for (quasi)reversible processes; E_p,a values are given for irreversible oxidation events.