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. Author manuscript; available in PMC: 2014 Jan 15.
Published in final edited form as: Water Res. 2012 Sep 18;46(19):6454–6462. doi: 10.1016/j.watres.2012.09.020

Table 1.

Properties of iron-containing minerals and observed-first order rate constants for mineral-catalyzed H2O2 decomposition.

Minerals Surface area (m2/g) Iron content (wt. %) kobs/m2(b)(c) (hr−1×m−2)
Goethite 19 62.9(a) 0.015
Hematite 30 70.0 0.032
Amorphous Fe-oxide 166 62.9(a) 0.097
Swy-2 32 2.6 0.022
NAu-2 69 26.2 0.012
Iron oxide-coated sand 5 1.0 0.199
FeSi-ox 521 12.3 0.007
FeAlSi-ox 423 10.9 0.003
(a)

Values were calculated based on the FeOOH formula.

(b)

The observed-first order rate constants (kobs) were obtained by fitting the experimental data to the first order decay reaction rate law. The r2 values of the fittings were always r2 > 0.99.

(c)

Rate constants were normalized by the total surface area of the solid used in the experiment.