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. Author manuscript; available in PMC: 2014 Jan 17.
Published in final edited form as: J Am Chem Soc. 2013 Jan 31;135(6):2198–2206. doi: 10.1021/ja308493k

Scheme 1. Summary of the Interceptions of the Catalytic Cycle of CODH ICh by Small-Molecule Inhibitorsa.

Scheme 1

aThe potentials −250 and −50 mV are the values observed for reactivation of enzyme with and without sulfide. The potential −520 mV is the standard potential for the CO2/CO half-cell reaction at pH 7.0.