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. Author manuscript; available in PMC: 2014 Feb 5.
Published in final edited form as: Chem Rev. 2013 Jun 14;113(8):6621–6658. doi: 10.1021/cr300463y

Scheme 3. Proposed Mechanisms for the Oxidation of CO to CO2 by [MoCu] CODHa.

Scheme 3

aA: Mechanism implicated by the structure of the n-BuNC-inhibited enzyme. B: Mechanism involving CO coordination to Cu and attack of Mo–O(H) on C atom of carbonyl.