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. Author manuscript; available in PMC: 2014 Feb 5.
Published in final edited form as: Chem Rev. 2013 Jun 14;113(8):6621–6658. doi: 10.1021/cr300463y

Scheme 8. Proposed Catalytic Cycle for Formate Production by Ir Complex with Pendant Base in Second Coordination Sphere (Cp* = C5Me5)a.

Scheme 8

aThe box represents a vacant coordination site.75p,q