Table 5.
Diallylation with Diarylmethanesa
![]() | |||||
|---|---|---|---|---|---|
| Entry | Pronucleophllu | Products | Yieldb (%) | ||
| 1c, d | 1b | ![]() |
6ba | 85 | |
| 2 | 1d | ![]() |
6da | 65 | |
| 3e | 4e | ![]() |
7ea | 85 | |
| 4f | 1f | ![]() |
6fa | 70 | |
| 5e | ![]() |
3aa | ![]() |
6aa | 84 |
| 6 | ![]() |
3ca | ![]() |
6ca | 80 |
| 7 | 8a | ![]() |
8aa | 90 | |
| 8 | 9a | ![]() |
9aa | 90 | |
Reaction conducted on a 0.1 mmol scale with 1 equiv of pro-nucleophile and 3 equiv of 2a at 0.1 M.
Isolated yield after chromatographic purification.
Reaction conducted at 0.066 M.
Reaction conducted at 50 °C.
3 equiv of KN(SiMe3)2 and 2 equiv of 2a.
8 equiv of KN(SiMe3)2.










