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. Author manuscript; available in PMC: 2014 Dec 25.
Published in final edited form as: Chem Commun (Camb). 2013 Dec 25;49(99):11588–11619. doi: 10.1039/c3cc47368f

Scheme 76.

Scheme 76

Asymmetric formation of cyclopentenes using phosphabicyclo[2.2.1]heptane.

a Reaction performed at 0 °C. b Reaction performed in toluene at 0 °C