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. Author manuscript; available in PMC: 2014 Dec 25.
Published in final edited form as: Chem Commun (Camb). 2013 Dec 25;49(99):11588–11619. doi: 10.1039/c3cc47368f

Scheme 89.

Scheme 89

Asymmetric formation of pyrrolidines and 2,3-dihydroindoles, catalyzed by the spirophosphepine 127.

a Reaction performed with 50 mol % of 2,4- dimethoxyphenol. b Reaction performed with 20 mol % of 2-fluoro-6-methoxyphenol.