Table 1.
Experimental6, 7 solubilities (g of peptide/100g of solution) and salting out constant ks for acetyltriglycine ethyl ester and triglycine in various Hofmeister salts at molar concentrations Cs of 1 M. The experimental definition of ks based on peptide solubility in water S(0) and in salt solution S(Cs) is as follows: ksCs = log(S(0)/ S(Cs)).
acetyltriglycine ethyl ester6 | triglycine7 | |||
---|---|---|---|---|
salt | solubility | ks (M−1) | solubility | ks (M−1) |
Water | 0.648 | 0 | 6.41 | 0 |
Na2SO4 | 0.18 | 0.55 | --- | --- |
NaAc | --- | --- | 7.44 | -0.06 |
NaF | 0.35 | 0.27 | --- | --- |
NaCl | 0.53 | 0.09 | 9.09 | -0.15 |
NaBr | 0.57 | 0.05 | 9.48 | -0.17 |
NaI | 0.87 | -0.13 | --- | --- |
NaSCN | 1.05 | -0.21 | --- | --- |
NaClO4 | 1.05 | -0.21 | --- | --- |