Table 1. Suzuki-Miyaura coupling of aryl halides with phenylboronic acid under Pd-P-300 catalysis.^[a] .

Entry	R	X	Yield (%)[b]
1	H	I	>99 (91)[c] (>99)[d]
2	Cl	I	98
3	4-C(O)CH3	I	>99
4	3-NO2	I	93
5	4-C(O)CH3	Br	98
6	2-C(O)CH3	Br	94
7	4-NO2	Br	79
8	2-NO2	Br	>99
9	4-CN	Br	93 (60)[c] (78)[d]
10	3-CN	Br	>99
11	4-CN	Cl	81 (9)[c] (35)[d]

^[a] Reaction conditions: aryl halide (0.6 mmol), phenylboronic acid (0.7 mmol), TBAB (1 mmol), Na₂CO₃ (2 mmol), Pd-P-300 (12 mol % Pd) in EtOH:H₂O (2 ml:1 ml), NMR characterisation of products available in supporting information.

^[b]Isolated yields after column chromatography with n-pentane.

^[c]Isolated yield for Palladium on Carbon 10%.

^[d]Isolated yield for palladium acetate.