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. 2014 Jan 29;8:6. doi: 10.1186/1752-153X-8-6

Table 1.

GS-MS chemical composition of the volatiles from the investigated Artemisia species

No RI Compound A. abrotanum plant % (mg/ml) A. abrotanum CH 2 Cl 2 % (mg/ml) A. dracunculus plant % (mg/ml) A. dracunculus CH 2 Cl 2 % (mg/ml) A. absinthium CH 2 Cl 2 % (mg/ml) A. vulgaris plant % (mg/ml) A. vulgaris % (mg/ml)
1.
 969
 4-Methyl-pent-2-enolid
 15.7 (1.7869)
 1.7 (0.1379)
 -
 1.8 (0.046)
 -
 -
 -
2.
 991
 1-Octen-3ol
 -
 -
 -
 -
 -
 -
 4.2 (0.253)
3.
 1037
 1,8-Cineol
 -
 -
 -
 -
 -
 -
 18 (1.077)
4.
 1043
 Z-β-Ocimene
 -
 -
 1.3 (0.103)
 -
 -
 -
 -
5.
 1044
 Lavender lactone
 2.6 (0.3017)
 -
 -
 -
 -
 -
 -
6.
 1053
 E-β-Ocimene
 -
 -
 1.6 (0.124)
 -
 -
 -
 -
7.
 1069
 cis-Arbusculone
 0.7 (0.0885)
 -
 -
 -
 -
 -
 -
8.
 1077
 trans-Arbusculone
 0.6 (0.0738)
 -
 -
 -
 -
 -
 -
9.
 1100
 trans-Sabinene hydrate
 -
 -
 -
 -
 -
 3.5 (0.079)
 -
10.
 1114
 Phenylethyl alcohol
 -
 -
 -
 -
 -
 1.8 (0.042)
 2.1 (0.129)
11.
 1122
 β-Thujone
 -
 -
 -
 -
 14.7 (0.380)
 -
 -
12.
 1129
 1-Terpineol
 1.6 (0.1817)
 -
 -
 -
 -
 -
 -
13.
 1132
 allo Ocimene
 -
 -
 0.3 (0.028)
 -
 -
 -
 -
14.
 1141
 iso-3-Thujanol
 -
 -
 -
 -
 2.2 (0.059)
 -
 -
15.
 1147
 cis-β-Terpineol
 1.2 (0.1402)
 0.8 (0.0700)
 -
 -
 -
 -
 -
16.
 1152
 Camphor
 -
 -
 -
 -
 -
 -
 5.6 (0.337)
17.
 1173
 Borneol
 -
 -
 -
 -
 -
 5.4 (0.122)
 13.2 (0.792)
18.
 1183
 Terpinen-4-ol
 -
 -
 -
 -
 -
 18.2 (0.407)
 13.5 (0.801)
19.
 1189
 p-Cymen-8-ol
 -
 -
 -
 -
 -
 -
 1.9 (0.113)
20.
 1195
 α-Terpineol
 -
 -
 -
 -
 -
 10 (0.223)
 6.6 (0.394)
21.
 1202
 Estragole
 0.9 (0.1123)
 0.8 (0.0702)
 84.1 (6.406)
 -
 5 (0.126)
 -
  
22.
 1211
 trans-Piperitol
 1.2 (0.1454)
 -
 -
 -
 -
 -
 -
23.
 1221
 trans-Carveole
 -
 -
 -
 -
 -
 1.9 (0.043)
 -
24.
 1226
 Nerol
 -
 -
 -
 -
 11.5 (0.297)
 -
 -
25.
 1227
 Nordavanone,
 3 (0.3414)
 5.4 (0.4275)
 -
 8.3 (0.206)
 -
 -
 -
26.
 1252
 Geraniol
 -
 -
 -
 -
 2.6 (0.069)
 -
 -
27.
 1253
 Chavicol
 -
  
 0.4 (0.031)
 1 (0.023)
 -
 -
 -
28.
 1257
 Piperitone
 0.5 (0.0616)
 -
 -
 -
 -
 -
 -
29.
 1260
 cis-Chrysanthenylacetate
 -
 -
 -
 -
 2.5 (0.065)
 -
 15 (0.897)
30.
 1292
 Cuminol
 -
 -
 -
 -
  
 7.2 (0.163)
 1.7 (0.105)
31.
 1299
 UnknownABS
  
  
  
  
 29.1 (0.750)
  
  
32.
 1331
 1.4-p-Menthadien-7-ol
 -
 -
 -
 -
  
 3.6 (0.082)
 1.7 (0.105)
33.
 1354
 Eugenol
 -
  
 1.4 (0.107)
 1.4 (0.036)
 0.9 (0.023)
 3.8 (0.086)
 3 (0.175)
34.
 1367
 UnknownABR1
  
 5.2 (0.4115)
 -
 -
 -
 -
 -
35.
 1386
 E-Methylcinnamate
 -
 -
 0.9 (0.068)
 -
 -
 -
 -
36.
 1399
 Methyleugenol
 -
  
 2.2 (0.173)
 1.4 (0.035)
 1.5 (0.040)
 -
 -
37.
 1401
 UnknownABR2
 1.3 (0.1540)
  
  
  
  
  
  
38.
 1422
 UnknownABR3
  
 20.7 (1.6363)
  
 4.3 (0.106)
  
  
  
39.
 1466
 γ-Decalactone
 -
 -
 0.2 (0.015)
 -
 -
 -
 -
40.
 1483
 Germacrene D
 -
 -
 0.2 (0.015)
 -
 -
 0.5 (0.011)
 1.6 (0.091)
41.
 1484
 Davanone ether
 0.9 (0.1016)
 -
 -
 -
 -
 -
  
42.
 1486
 Farnesene
 -
 -
 -
 -
 -
 -
 1(0.062)
43.
 1491
 β-Selinene
 -
 -
 -
 -
 -
 -
 1.2 (0.076)
44.
 1500
 Bicyclogermacrene
 -
 -
 0.1 (0.012)
 -
 -
 -
 -
45.
 1504
 Davana ether*
 3.2 (0.3591)
 -
 -
 -
 -
 -
 -
46.
 1518
 Artedouglasia oxide C
 1.7 (0.1932)
 1.1 (0.0869)
  
 1.7 (0.042)
  
  
  
47.
 1520
 δ-Cadinene
 -
 -
 -
 -
 -
 -
 1.5 (0.093)
48.
 1522
 Davana ether*
 1.4 (0.1581)
 -
 -
 -
 -
 -
 -
49.
 1531
 Artedouglasia oxide A
 2.2 (0.2575)
 1.8 (0.1486)
 -
 3.4 (0.084)
 -
 -
 -
50.
 1554
 Artedouglasia oxide D
 1 (0.1201)
 0.6 (0.0534)
 -
 1 (0.023)
 -
 -
 -
51.
 1476
 Artedouglasia oxide B
 1.3 (0.1469)
 1 (0.0858)
 -
 1.6 (0.040)
 -
 -
 -
52.
 1580
 cis-Davanone
 5.2 (0.5989)
 7.4 (0.5896)
 0.6 (0.048)
 9.1 (0.225)
 -
 -
 -
53.
 1589
 Spathulenol
 -
 -
 -
 -
 6.5 (0.168)
 12.1 (0.271)
 7.1 (0.425)
54.
 1585
 Caryophyllene oxide
 -
 -
 -
 -
 2.8 (0.072)
 8.5 (0.191)
 2.7 (0.163)
55.
 1598
 UnknownABR4
 -
 2 (0.1582)
 -
 -
 -
 -
 -
56.
 1599
 UnknownABR5
 1.3 (0.1570)
 -
 -
 -
 -
 -
 -
57.
 1641
 UnknownABR6
 2.7 (0.3121)
 -
 -
 -
 -
 -
 -
58.
 1655
 Bisabololoxide B
 -
 -
 -
 -
 3.3 (0.086)
 -
 -
59.
 1656
 epi-α Muurolol
 -
 -
 -
 -
 -
 11.8 (0.265)
 -
60.
 1684
 α-Bisabolol
 -
 -
 -
  
 11 (0.285)
 -
 -
61.
 1685
 UnknownABR7
 12.4 (1.4113)
 17.2 (1.3599)
 0.5 (0.041)
 20.5 (0.506)
 -
 -
 -
62.
 1688
 UnknownABR8
 4 (0.4598)
 -
 -
 -
 -
 -
 -
63.
 1711
 UnknownABR9
 8.7 (0.9892)
 -
 -
 3.4 (0.085)
 -
 -
 -
64.
 1719
 Herniarin,
 -
 -
 4.3 (0.329)
 10 (0.246)
 5.8 (0.150)
 -
 -
65.
 1754
 Davanone Derivative
 22.5 (2.5593)
 33.3 (2.6535)
 -
 18.2 (0.450)
 -
 -
 -
66.
 1936
 UnknownDRA
 -
 -
 0.3 (0.029)
 7 (0.174)
 -
 -
 -
67.
 1963
 Hexadecanoic acid
 -
 -
 -
 -
 -
 11.2 (0.249)
 -
68. 2107 Phytol-isomer 1.2 (0.1451) - 1.1 (0.087) (0.138) - - -

* exact isomer not determined, RI retention index.

Mass spectra of the unidentified compounds.

RI 1367 UnknownABR1: 41 (50), 43 (72), 44 (13), 45 (14), 53 (15), 55 (100), 56 (13), 57 (30), 67 (32), 68 (13), 69 (37), 71 (41), 74 (11), 81 (19), 83 (14), 84 (11), 85 (11), 93 (37), 95 (25), 111 (34), 123 (10), 169 (46).

RI 1299 UnknownABS: 41 (39), 43 (68), 44 (8), 53 (16), 55 (22), 57 (14), 59 (100), 67 (49), 68 (19), 69 (9), 71 (34), 77 (11), 79 (32), 81 (45), 82 (55), 83 (12), 89 (11), 93 (7), 94 (7), 109 (10), 152 (11).

RI 11401 UnknownABR2: 55 (100), 41 (70), 43 (100), 44 (25), 53 (16), 56 (14), 57 (55), 59 (26), 67 (31), 69 (44), 71 (34), 77 (12), 81 (29), 83 (26), 85 (19), 91 (18), 93 (96), 95 (15), 97 (20), 111 (68), 125 (15), 126 (26).

RI 1422 UnknownABR3: 41 (32), 43 (62), 53 (13), 55 (83), 57 (10), 67 (24), 68 (14), 69 (28), 71 (100), 72 (14), 77 (10), 81 (24), 83 (16), 91 (14), 93 (74), 95 (9), 100 (19), 110 (11), 111 (94), 125 (18), 195 (11).

RI 1598 UnknownABR4: 41 (9), 42 (3), 43 (10), 44 (3), 53 (4), 55 (13), 57 (6), 67 (5), 68 (3), 69 (5), 71 (4), 79 (2), 81 (4), 83 (5), 85 (100), 86 (5), 93 (9), 107 (2), 111 (3), 114 (12), 156 (4).

RI 1599 UnknownABR5: 41 (38), 43 (100), 44 (14), 55 (30), 57 (25), 69 (22), 71 (17), 77 (14), 79 (20), 81 (32), 83 (22), 85 (20), 91 (15), 93 (18), 95 (17), 109 (45), 149 (14), 161 (15), 207 (46), 219 (21), 234 (15).

RI 1641 UnknownABR6: 41 (52), 43 (68),44 (13), 53 (18), 55 (100), 56 (13), 57 (29), 67 (27), 68 (18), 69 (37), 71 (23), 79 (12), 81 (27), 83 (32), 84 (17), 85 (12), 91 (12), 93 (72), 95 (24), 109 (13), 111 (73).

RI 1685 UnknownABR7: 41 (38), 43 (40), 53 (9), 55 (53), 57 (10), 67 (15), 68 (10), 69 (43), 71 (18), 77 (6), 81 (17), 83 (20), 91 (9), 93 (64), 94 (7), 95 (8), 97 (9), 111 (100), 112 (12), 125 (19), 140 (13).

RI 1688 UnknownABR8: 41 (62), 43 (100), 53 (15), 55 (82), 57 (23), 67 (31), 68 (28), 69 (43), 70 (16), 71 (77), 72 (19), 79 (12), 81 (31), 82 (15), 83 (20), 91 (13), 93 (93), 94 (14), 95 (24), 110 (15), 111 (76), 113 (13), 125 (20).

RI 1711 UnknownABR9: 43 (100), 93 (66), 55 (55), 111 (55), 113 (51), 85 (39), 41 (35), 69 (30), 67 (26), 95 (25), 81 (24), 125 (20), 57 (20), 71 (19), 97 (17), 96 (17), 109 (14), 83 (14), 68 (14), 138 (11), 53 (11), 236 (5).

RI 1754 Davanone-derivative: 41 (45). 43 (100), 53 (17), 55 (74), 57 (24), 67 (32), 68 (14), 69 (45), 71 (36), 79 (18), 81 (48), 82 (12), 83 (23), 91 (12), 93 (87), 95 (20), 96 (29), 97 (48), 109 (20), 111 (90), 112 (12), 113 (15), 125 (69), 236 (36).

RI 136 UnknownDRA: 41 (40), 43 (12), 53 (22), 55 (23), 57 (17), 66 (23), 67 (28), 69 (25), 77 (12), 79 (18), 81 (84), 82 (9), 83 (12), 95 (21), 96 (74), 98 (14), 110 (17), 113 (13), 151 (100), 152 (37), 22.