Table 1.
Baeyer-Villiger oxidation.
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|---|---|---|---|
| Enzyme | Gene | Expression system | Referencesa |
| CHMO | chmo from Polaromonas sp. JS666 | E. coli BL21 Star (DE3)/pET101/D-TOPO vector | Alexander et al., 2012 |
| mutants of chnB from A. calcoaceticus NCIMB 9871 | E. coli BL21-Gold (DE3)/pET22b | Opperman and Reetz, 2010 | |
| chnB from A. calcoaceticus NCIMB 9871 and pos5 (NADH kinase) from S. cerevisiae CEN.PK2-1D | E. coli BL21(DE3)/pET22b (chnB) and ACYCDuet-1 (pos5) | Lee et al., 2013 | |
| chnB from A. calcoaceticus NCIMB 9871 and gapB (NADP+-dependent GAPDH) from B. subtilis | E. coli (gapA null, NAD+-dependent glyceraldehyde-3-phosphate dehydrogenase mutant)/pET22b (chnB) and pDHC29 (gapB) | Wang et al., 2013 | |
| PAMO | different pamO mutants from T. fusca | E. coli TOP10/pBAD/myc-HisA | Wu et al., 2010 |
| different mutant pamO from T. fusca | E. coli TOP10/pBAD/myc-HisA | Dudek et al., 2011 | |
| wild-type and mutant pamO from T. fusca | E. coli TOP10/pBAD-Tat-AldO (periplasmic expression) | Dudek et al., 2013a, b | |
| BVMO | 22 bvmo genes from R. jostii RHA1 (16 BVMOs with demonstrated activity) | E. coli TOP10/pBADN and pCRE2 (with phosphite dehydrogenase gene) | Riebel et al., 2012 |
| bvmo from A. radioresistens S13 | E. coli BL21(DE3)/pT7 expression vector | Minerdi et al., 2012 | |
| STMO | wild-type and mutant stmo from R. rhodochrous | E. coli BL21(DE3) CodonPlus/Champion pET-vector | Franceschini et al., 2012 |
| wild-type stmo from R. rhodochrous | E. coli BL21(DE3)/pET28b | Leipold et al., 2013 | |
| SAPMO | SAPMO from C. testosteroni KF1 | E. coli BL21 Star (DE3)/pET101/D-TOPO vector | Weiss et al., 2013 |
| OTEMO | OTEMO gene from P. putida NCIMB 10007 | E. coli BL21(DE3)/pET28b | Kadow et al., 2012 |
| OTEMO gene from P. putida ATCC 17453 | E. coli BL21(DE3)/pSD80 | Leisch et al., 2012 | |
| 2,5-DKCMO | 2,5-DKCMO gene from P. putida NCIMB 10007 | E. coli BL21(DE3)/pET28b | Kadow et al., 2011, 2012 |
| 3,6-DKCMO | 3,6-DKCMO gene from P. putida NCIMB 10007 | E. coli BL21(DE3)/pET28b (coexpression of GroES-GroEL chaperones) | Kadow et al., 2012 |
| 2,5- and 3,6-DKCMO | 2,5- and 3,6-DKCMO genes from P. putida NCIMB 10007 and Fre gene from E. coli | E. coli BL21(DE3)/pET28b (DKCMOs, coexpression of GroES-GroEL); pGas (Fre or fusion genes, L-rhamnose inducible) | Kadow et al., 2013 |
| BVMO type II | camE25−1, camE25−2, camE36 and Fred gene from P. putida ATCC 17453 | E. coli BL21(DE3)/pSD80 (each camE gene and tandem clones); E. coli BL21(DE3) pLysS/pET17b (Fred gene) | Iwaki et al., 2013 |
| FMO (type II) | fmo from S. maltophilia | E. coli BL21(DE3)/pET-YSBL-LIC-3C | Jensen et al., 2012 |
| several fmo genes from R. jostii RHA1 | E. coli/pBADN and pCRE2 | Riebel et al., 2013a, b | |
a
The information shown corresponds to reports as of 2010.
Abbreviations: 3,6-DKCMO, 3,6-diketocamphane 1,6-monooxygenase; 2,5-DKCMO, 2,5-diketocamphane 1,2-monooxygenase; ACMO, acetone monooxygenase; BVMO, Baeyer-Villiger monooxygenase; CDMO, cyclododecanone monooxygenase; CHMO, cyclohexanone monooxygenase; CPMO, cyclopentanone monooxygenase; FMO, flavin-containing monooxygenase; OT, 2-oxo-Δ3-4,5,5-trimethylcyclopentenylacetic acid; OTEMO, 2-oxo-Δ3-4,5,5-trimethylcyclopentenylacetyl-CoA monooxygenase; PAMO, phenylacetone monooxygenase; SAPMO, 4-sulfophenyl acetate monooxygenase; STMO, steroid monooxygenase.