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. Author manuscript; available in PMC: 2015 Jan 8.
Published in final edited form as: J Am Chem Soc. 2013 Dec 16;136(1):48–51. doi: 10.1021/ja410704d

Table 1.

Regiodivergent opening of epoxides.a

graphic file with name nihms550409t1.jpg

entry additives yield (%) 2:3
1 none 9 ND
2 50 mol % NaI, 20 mol % py 50 91:9
3 10 mol % Cp2TiCl2 40 1:4
a

See Tables 2 and 4 for conditions. Yield and ratio of 2:3 determined by GC analysis vs. internal standard, uncorrected.