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. Author manuscript; available in PMC: 2014 Dec 28.
Published in final edited form as: Org Biomol Chem. 2013 Nov 5;11(48):8419–8425. doi: 10.1039/c3ob41898g

Table 2.

Second-order rate constants for the retro-aldol reaction of methodol at pH 7.5 using different catalysts.

Catalyst k2 (M−1 s−1) Relative k2
BuAm 2.1 × 10−6 (1)
CTAC/BuAm 2.5 × 10−4 120
CTAC/OcAm 1.5 × 10−3 710
CTAC/DoAm 2.0 × 10−2 9,500
RA-61 0.49* 230,000
BSA 1.8 × 10−2 8,500
*

value from ref. 8.