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. Author manuscript; available in PMC: 2015 Feb 1.

Published in final edited form as: J Mol Liq. 2014 Feb;190:34–41. doi: 10.1016/j.molliq.2013.09.025

Table 1.

Limiting molar conductivities, Λ^∞, and association constants, $K_{A}^{\circ}$ of investigated alkali metal halides in water. The assumed upper limit of association, R, is indicated.

T	Λ ^∞	$K_{A}^{\circ}$	Λ ^∞	$K_{A}^{\circ}$	Λ ^∞	$K_{A}^{\circ}$	Λ ^∞	$K_{A}^{\circ}$
K	S · cm² · mol⁻¹	mol⁻¹ ·dm³	S · cm² · mol⁻¹	mol⁻¹ ·dm³	S · cm² · mol⁻¹	mol⁻¹ ·dm³	S · cm² · mol⁻¹	mol⁻¹ ·dm³

	LiCl, R/nm=0.538		NaCl,^a R/nm=0.559		KC1, R/nm=0.594		RbCl, R/nm=0.610
278.15	70.49±0.03	0.71 ±0.16	77.75±0.02	1.33±0.22	94.33±0.03	1.66±0.13	97.76±0.03	1.24±0.12
	70.27^b		77.80^b		94.23^b		97.62^b
283.15	80.98±0.05	0.90±0.20	89.16±0.02	1.58±0.22	107.45±0.04	1.62±0.13	111.03±0.05	1.06±0.17
	80.67^b		89.21^b		107.36^b		110.97^b
288.15	91.69±0.06	0.10±0.23	101.11±0.01	1.62±0.13	121.10±0.04	1.57±0.13	124.97±0.05	1.17±0.13
	91.63^b		101.14^b		121.03^b		124.88^b
293.15	103.21±0.06	0.32±0.20	113.58±0.02	1.70±0.15	135.27±0.05	1.49±0.13	139.37±0.06	1.23±0.16
	103.07^b		113.58^b		135.21^b		139.28^b
298.15	115.21±0.06	0.44±0.17	126.55±0.01	1.58±0.07	149.94±0.04	1.47±0.10	154.21±0.06	1.26±0.15
	114.99^b		126.50^b		149.85^b		154.16^b
303.15	127.61 ±0.05	0.56±0.13	139.96±0.01	1.65±0.08	164.96±0.04	1.41±0.10	168.51±0.07	1.50±0.16
	127.36^b		139.89^b		164.93^b		169.46^b
308.15	140.39±0.03	0.61±0.08	153.79±0.02	1.59±0.10	180.49±0.09	1.77±0.18	185.02±0.08	1.60±0.16
	140.16^b		153.73^b		180.40^b		185.15^b
313.15	153.40±0.05	1.45±0.10			196.13±0.09	2.53±0.17	200.72±0.11	2.09±0.20
	153.37^b				196.25^b		201.17^b

	CsCl, R/nm=0.626		Nal, R/nm=0.598		Csl, R/nm=0.665		KI, R/nm=0.633
278.15	97.74±0.04	1.69±0.14	79.07±0.05	0.79±0.24	98.53±0.05	1.53±0.21
	97.50^b		78.92^b		98.62^b
283.15	110.62±0.05	0.76±0.14	90.30±0.04	0.58±0.15	111.46±0.04	1.47±0.17
	110.80^b		90.18^b		111.78^b
288.15	124.42±0.06	0.86±0.14	102.11±0.04	0.060±0.14	125.03±0.05	1.39±0.16
	124.61^b		101.98^b		125.44^b
293.15	138.69±0.06	0.88±0.14	114.44±0.08	0.53±0.22	138.98±0.08	0.97±0.24
	138.88^b		114.27^b		139.58^b
298.15	153.47±0.07	1.00±0.15	127.16±0.06	0.34±0.15	153.64±0.05	1.33±0.13	150.50±0.09	0.71±0.26
	153.61^b		127.05^b		154.16^b	150.40*
303.15	168.57±0.07	0.96±0.13	140.33±0.09	0.43±0.22	168.45±0.07	1.30±0.19
	168.76^b		140.28^b		169.15^b
308.15	183.89±0.07	0.76±0.14	153.91±0.12	0.68±0.28	183.59±0.08	1.30±0.18
	184.31^b		153.94^b		184.51^b
313.15	199.45±0.08	1.19±0.15	167.63±0.12	1.27±0.24	198.83±0.09	1.87±0.20
	200.23^b		168.0^b1		200.23^b

^a

Reevaluated form the literature data [58]

^b

Harned Owen