Figure - PMC

Skip to main content

View full-text article in PMC

. Author manuscript; available in PMC: 2014 Nov 1.

Published in final edited form as: ACS Catal. 2013 Nov 1;3(11):2599–2605. doi: 10.1021/cs400689a

(A) X-ray structure of [(bpy)Cu(OH)]₂(OTf)₂, which crystallizes as a dimer of dimers (see Supporting Information for details). The triflate counterions are omitted for clarity. (B) The oxidation of CyCH₂OH by Cu^IOTf () and [(bpy)Cu(OH)]₂(OTf)₂. (). Data were obtained by monitoring pressure changes during catalytic turnover. Reaction conditions: 10 mM (bpy)Cu, 10 mM TEMPO, 20 mM NMI: 0.2 M CyCH₂ OH, 1 atm O₂, 2.5 mL MeCN, 27 °C.

Inline graphic — (A) X-ray structure of [(bpy)Cu(OH)]₂(OTf)₂, which crystallizes as a dimer of dimers (see Supporting Information for details). The triflate counterions are omitted for clarity. (B) The oxidation of CyCH₂OH by Cu^IOTf () and [(bpy)Cu(OH)]₂(OTf)₂. (). Data were obtained by monitoring pressure changes during catalytic turnover. Reaction conditions: 10 mM (bpy)Cu, 10 mM TEMPO, 20 mM NMI: 0.2 M CyCH₂ OH, 1 atm O₂, 2.5 mL MeCN, 27 °C.