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. Author manuscript; available in PMC: 2014 Nov 1.

Published in final edited form as: ACS Catal. 2013 Nov 1;3(11):2599–2605. doi: 10.1021/cs400689a

Dependence of Cu^IOTf/bpy/TEMPO/NMI catalyzed benzyl alcohol oxidation on added (A) NMIH⁺ OTf⁻ and (B) DBUH⁺ OTf⁻. The reaction catalyzed by Cu^II(OTf)₂/bpy/-TEMPO/NMI () is included in A for comparison. Rates were obtained by monitoring pressure changes during catalytic turnover. Standard reaction conditions: 10 mM Cu^I(OTf), 10 mM bpy, 20 mM NMI, 10 mM TEMPO, 0.2 M alcohol.

Inline graphic — Dependence of Cu^IOTf/bpy/TEMPO/NMI catalyzed benzyl alcohol oxidation on added (A) NMIH⁺ OTf⁻ and (B) DBUH⁺ OTf⁻. The reaction catalyzed by Cu^II(OTf)₂/bpy/-TEMPO/NMI () is included in A for comparison. Rates were obtained by monitoring pressure changes during catalytic turnover. Standard reaction conditions: 10 mM Cu^I(OTf), 10 mM bpy, 20 mM NMI, 10 mM TEMPO, 0.2 M alcohol.