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. Author manuscript; available in PMC: 2014 Feb 25.
Published in final edited form as: J Am Chem Soc. 2013 Jun 6;135(24):9186–9194. doi: 10.1021/ja403965h

Figure 4.

Figure 4

(a) Absorption spectral changes observed in electron transfer from [RuII(bpy)]2+ (5.0 × 10−3 M) to [(Bn-TPEN)-MnIV(O)]2+–Sc3+ (5.0 × 10−4 M) in CF3CH2OH/CH3CN (v/v = 1:1) at 273 K. (b) Plot of concentration of [RuIII(bpy)3]3+ produced in electron transfer from [RuII(bpy)3]2+ to [(Bn-TPEN)MnIV(O)]2+– Sc3+ vs initial concentration of [RuII(bpy)3]2+, [[RuII(bpy)3]2+]0.