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. Author manuscript; available in PMC: 2014 Feb 25.
Published in final edited form as: J Am Chem Soc. 2013 Jun 6;135(24):9186–9194. doi: 10.1021/ja403965h

Table 2.

One-Electron Reduction Potentials (Ered) and Reorganization Energies (λ) of Electron-Transfer Reduction of [MnIV(O)]2+, [MnIV(O)]2+–(Sc3+)1, and [MnIV(O)]2+– (Sc3+)2

complex Ered, V vs SCE λ, eV
[(Bn-TPEN)MnIV(O)]2+ 0.78 ± 0.01a 2.24 ± 0.03a
[(Bn-TPEN)MnIV(O)]2+–(Sc3+)1 1.28 ± 0.02
[(Bn-TPEN)MnIV(O)]2+–(Sc3+)2 1.36 ± 0.02 2.12 ± 0.02
[(N4Py)MnIV(O)]2+ 0.80 ± 0.01 2.27 ± 0.03
[(N4Py)MnIV(O)]2+–(Sc3+)1 1.31 ± 0.02
[(N4Py)MnIV(O)]2+–(Sc3+)2 1.42 ± 0.01 2.21 ± 0.02
a

Taken from ref 41b.