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. Author manuscript; available in PMC: 2014 Feb 28.
Published in final edited form as: J Am Soc Mass Spectrom. 2011 Oct 5;22(12):2160–2170. doi: 10.1007/s13361-011-0240-7

Scheme 1.

Scheme 1

The fragmenation pathways proposed for the [M + Na]+ ions of 6-mycolyl-α,α'-D-trehalose (TMM) (the indicated m/z values are ions seen for18:0/16:0-TMM, which is one of the 3 isomers that give rise to the [M+Na]+ of m/z 871)