Table 3. Selected Bond Distances (Å) and Bond Angles in Compounds 1–8.
| atom1–atom2 | 1 | 2a | 3 | 4 | 5 | 6b | 7b | 8 |
|---|---|---|---|---|---|---|---|---|
| Ru–O1 | 2.001(3) | 2.009(5), 1.993(9) | 1.997(5) | 1.998(1) | 1.988(4) | 2.008(2), 2.011(3) | 2.011(3), 2.009(1) | 2.019(3) |
| Ru–N1 | 2.051(4) | 2.078(6), 2.073(4) | 2.097(6) | 2.107(2) | 2.132(6) | 2.068(1), 2.074(7) | 2.078(3), 2.086(8) | 2.077(3) |
| Ru–N2 | 1.702(4) | 1.707(6), 1.714(3) | 1.731(7) | 1.725(2) | 1.726(6) | 1.7256(17), 1.7249(7) | 1.732(4), 1.729(3) | 1.730(3) |
| N2–O3 | 1.149(6) | 1.178(8), 1.164(7) | 1.158(8) | 1.147(2) | 1.141(7) | 1.149(2), 1.1485(5) | 1.145(5), 1.147(2) | 1.137(3) |
| Ru–Cl1 | 2.361(2) | 2.376(2), 2.367(3) | 2.363(2) | 2.3756(4) | 2.383(2) | 2.3724(4), 2.374(1) | 2.365(1), 2.369(4) | 2.3771(7) |
| Ru–Cl2 | 2.361(2) | 2.370(2), 2.381(6) | 2.376(2) | 2.3803(4) | 2.368(2) | 2.3539(4), 2.36(1) | 2.367(1), 2.3664(9) | 2.3713(8) |
| Ru–Cl3 | 2.380(1) | 2.364(2), 2.360(5) | 2.374(2) | 2.3636(5) | 2.383(2) | 2.3789(4), 2.37(3) | 2.376(1), 2.371(4) | 2.3732(6) |
| atom1–atom2–atom3 | ||||||||
| O1–Ru–N1 | 80.1(1) | 80.0(2), 81.0(4) | 80.5(2) | 80.67(5) | 81.4(2) | 79.35(6), 79.2(1) | 80.0(1), 79.7(3) | 81.28(9) |
| Ru–N2–O3 | 179.1(5) | 171.9(6), 176(1) | 177.7(6) | 176.52(16) | 176.4(6) | 178.30(2), 177.5(9) | 174.1(3), 174.8(7) | 179.4(3) |
| Cl2–Ru–Cl3 | 172.77(5) | 173.71(7), 173.1(5) | 173.96(8) | 174.90(2) | 175.37(7) | 172.42(2), 172.9(5) | 173.93(4), 173.1(6) | 172.74(3) |
a
Parameters for one of the six crystallographically independent complex anions and average values are quoted.
b
Parameters for one of the two crystallographically independent complex anions and average values are quoted.