Table 5.
Gas chromatography-mass spectroscopy analysis of bio-oil products of duckweed, azolla and microalgae pyrolysis
| Retention time, minutes | Duckweed | Azolla (green) | Azolla (red) | Microalgae |
|---|---|---|---|---|
| 4.3 |
|
|
Toluene |
Toluene |
| 4.9 |
|
|
3-Methyl furan and/or 3-Cyclopenten-1,2 diol |
|
| 5.2 |
|
|
Tetrahydro-4H-pyran-4-ol |
|
| 5.5 |
|
|
4-Cyclohexene-1,2-diol |
|
| 5.58 |
|
|
|
2-Methyl-1H-Pyrrole |
| 5.72 |
|
2,4,5-Trimethyl 1H-imidazole |
|
|
| 5.8 |
|
|
1,2-Diemthyl-2-pyrroline |
|
| 6.18 |
|
|
|
Piperidine |
| 6.33 |
|
Phenol |
Phenol |
Phenol |
| 6.72 |
2,3-Dimethyl-1H-Pyrrole |
|
|
2,3-Dimethyl-1H-Pyrrole |
| 6.83 |
|
|
|
4-Ethyl-2-methyl-1H- pyrrole |
| 7.38 |
2-Methyl phenol |
2-Methyl phenol |
2-Methyl phenol |
|
| 7.9 |
3-Methyl phenol |
3-Methyl phenol |
3-Methyl phenol |
|
| 8.3 |
|
|
|
3-Ethyl-2,5-dimethyl-1H-pyrrole |
| 8.38 |
|
|
|
3-Ethyl-2,4-dimethyl-1H-pyrrole |
| 8.77 |
4-Methyl phenol |
|
|
|
| 9.28 |
|
|
Dodecane |
|
| 9.33 |
|
|
|
2-Isopropylpyrazine |
| 9.43 |
|
|
|
3-Ethyl-2,4,5-Trimethyl-1H-Pyrrole |
| 9.67 |
4-Ethyl phenol |
|
|
|
| 10.13 |
2-Ethyl phenol |
|
|
|
| 10.67 |
|
Tridecane |
Tridecane |
|
| 10.83 |
|
|
|
Indole |
| 11.77 |
Indolizine |
Indolizine |
Indolizine |
|
| 11.98 |
|
Tetradecane |
Tetradecane |
Tetradecane |
| 12.83 |
3-Methyl Indolizine |
|
|
3-Methyl Indolizine |
| 13.23 |
|
Pentadecane |
Pentadecane |
Pentadecane |
| 13.37 |
4-Methyl 1H-indole |
|
|
|
| 14.43 |
|
Hexadecane |
Hexadecane |
Hexadecane |
| 15.28 |
|
|
|
6,9-Heptadecadiene |
| 15.37 |
|
|
|
1,15-Pentadecanediol |
| 15.38 |
|
|
|
8-Heptadecane |
| 15.57 |
|
Heptadecane |
Heptadecane |
Heptadecane |
| 15.93 |
3,7,11,15-Tetramethyl-2-hexadecene |
3,7,11,15-Tetramethyl-2-hexadecene |
3,7,11,15-Tetramethyl-2-hexadecene |
3,7,11,15-Tetramethyl-2-hexadecene |
| 16.65 |
|
Octadecane |
Octadecane |
|
| 17.1 to 17.55 |
Isomers of 3,7,11,15-Tetramethyl-2-hexadecen-1-ol (phytol) |
Various isomers of 3,7,11,15-Tetramethyl-2-hexadecen-1-ol (phytol) |
Various isomers of 3,7,11,15-Tetramethyl-2-hexadecen-1-ol (phytol) |
Various isomers of 3,7,11,15-Tetramethyl-2-hexadecen-1-ol (phytol) |
| 17.8 |
|
|
|
Nonadecane |
| 18.25 |
|
Palmitoleic acid |
Palmitoleic acid |
|
| 18.65 |
|
Eicosane (C20) |
|
|
| 19.58 |
|
Heneicosane (C21) |
|
|
| 19.75 | Linolenic acid |