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. Author manuscript; available in PMC: 2014 Nov 11.
Published in final edited form as: Chemistry. 2013 Oct 2;19(46):15645–15651. doi: 10.1002/chem.201301423

Table 1.

Critical micelle concentrations (CMCs) and hydrodynamic radii (Rh) of the micelles (mean ± SD, n = 4) for tripod amphiphiles (TPA-2, TPA-2-S, TPA-5, TPA-5-1 and TPA-5-2) and conventional detergents (DDM and OG).

Amphiphiles MW[a] CMC (mM) CMC (wt %) Rh (nm)[b]
TPA-2 659.8 ~3.6 ~0.24 2.0 ± 0.06
TPA-2-S 665.8 ~1.8 ~0.12 3.3 ± 0.06
TPA-5 984.0 ~8.0 ~0.78 6.0 ± 0.12[c]
TPA-5-1 1040.0 ~0.30 ~0.031 2.7 ± 0.02
TPA-5-2 1011.1 ~0.021 ~0.002 2.8 ± 0.01
DDM 510.1 ~0.17 ~0.0087 3.5 ± 0.03
OG 292.4 ~25 0.73 1.5~2.3[d]
[a]

Molecular weight of detergents.

[b]

Hydrodynamic radius of micelles as determined at 1.0 wt %.

[c]

Two forms of aggregates were observed with hydrodynamic radii of ~2.2 nm and ~75 nm (see Figure S2).

[d]

These values were obtained from the literature.[8]