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Potential energy profiles of the rotation around the C6-C7 bond of OMP analogs. (A) Profile of 1-methyl-orotate methyl ester, a model compound for OMP methyl ester. Blue and red lines indicate the profiles for anti and syn conformations of the methyl group, respectively, whose chemical formulae are also shown. (B) Profile of the carboxylate group rotation in 1-methyl-orotate.
