Skip to main content
. 2014 Jan 8;53(2):1021–1031. doi: 10.1021/ic4024713

Table 1. Electrochemical Data from Cyclic Voltammetrya.

compound Eox2 (V) Eox1 (V) Ered1 (V) Ered2 (V) ΔEneu (V)b
1c 0.60 –0.09 –1.19 –1.73 1.10
2(PF6)   0.33 –0.54   0.87
3d 0.93e 0.12 –0.94 –1.75 1.06
a

Half-wave potentials from cyclic voltammetric measurements in CH2Cl2/0.1 M Bu4NPF6 for reversible processes at 298 K with a scan rate of 100 mV s–1. Ferrocene/ferrocenium was used as the internal standard.

b

ΔEneu = Eox1Ered1.

c

From ref (7d) (values have been corrected).

d

From ref (7b).

e

Epa for the irreversible process.