Table 1. Electrochemical Data from Cyclic Voltammetrya.
compound | Eox2 (V) | Eox1 (V) | Ered1 (V) | Ered2 (V) | ΔEneu (V)b |
---|---|---|---|---|---|
1c | 0.60 | –0.09 | –1.19 | –1.73 | 1.10 |
2(PF6) | 0.33 | –0.54 | 0.87 | ||
3d | 0.93e | 0.12 | –0.94 | –1.75 | 1.06 |
Half-wave potentials from cyclic voltammetric measurements in CH2Cl2/0.1 M Bu4NPF6 for reversible processes at 298 K with a scan rate of 100 mV s–1. Ferrocene/ferrocenium was used as the internal standard.
ΔEneu = Eox1 – Ered1.
From ref (7d) (values have been corrected).
From ref (7b).
Epa for the irreversible process.