Table 1.
Arrhenius Parameters Derived from Fits of the 1/T1 Data.
| Compound | Group causing the relaxation | Ea (kcal/mol) | τ0−1 (s−1) | C (s−2) |
|---|---|---|---|---|
| 3 | OMe + BCO | 2.5a | ||
| OMeb | 3.2 | 1.0 × 1012* | 1.0 × 108* | |
| 3-d6 | BCO | 1.15c | 2.5 × 1011* | 6.8 × 108* |
| 8 | OMe | 1.9 | 1.9 × 1011 | 1.4 × 108 |
| 8-d3 | Me | 1.35c | 3.3 × 1011* | 1.7 × 108* |
Apparent activation energy resulting from contributions of two groups.
Obtained from the difference between compounds 3 and 3-d6 (SI, Figure S8)
Obtained from linear regression of the data.
Resulting from 1/T1 data extrapolation using the Kubo-Tomita expression.