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An enzyme involved in type I PKS biosynthesis may be utilized in lomaiviticin starter unit generation. A) Natural products synthesized by type I PKS-nonribosomal peptide synthetase assembly lines contain β-propionyl and -ethyl branching. B) Role of acyltransferase/decarboxylase (AT/DC) LnmK in leinamycin biosynthesis. C) Hypothesized role of LnmK homolog Lom62 in lomaiviticin biosynthesis.
