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. 2014 Mar 7;12(3):1298–1316. doi: 10.3390/md12031298

Table 3.

1H and 13C NMR chemical shifts of the constituents of the O-specific polysaccharides (OPS) of A. veronii strain Bs19. Spectra were recorded in D2O relative to external acetone as reference (δH 2.225, δC 31.45).

Chemical Shifts (ppm)
Sugar Residue H-1 H-2 H-3 H-4 H-5 H-6
C-1 C-2 C-3 C-4 C-5 C-6
→3)-α-d-GalpNAc-(1→ A 5.27 4.35 3.95 4.24 4.11 3.75
98.11 49.15 78.33 69.72 72.30 62.30
→3)-α-l-Rhalp-(1→ B 5.21 4.28 3.87 3.61 3.78 1.33
102.46 68.34 77.14 71.21 70.71 18.00
→4)-α-d-Quip3NAc-(1→ C 5.05 3.56 4.33 3.52 4.20 1.30
96.03 71.50 55.09 77.44 68.24 19.00
→4)-β-d-Galp-(1→ D 4.47 3.54 3.77 4.03 3.74 3.75
106.02 71.45 74.17 77.04 76.06 62.30

Chemical shifts for NAc were δH 2.02 and δC 23.7/175.6 for A and δH 1.97 and δC 23.2/175.4 for C.