Table 3.
Chemical Shifts (ppm) | |||||||
---|---|---|---|---|---|---|---|
Sugar Residue | H-1 | H-2 | H-3 | H-4 | H-5 | H-6 | |
C-1 | C-2 | C-3 | C-4 | C-5 | C-6 | ||
→3)-α-d-GalpNAc-(1→ | A | 5.27 | 4.35 | 3.95 | 4.24 | 4.11 | 3.75 |
98.11 | 49.15 | 78.33 | 69.72 | 72.30 | 62.30 | ||
→3)-α-l-Rhalp-(1→ | B | 5.21 | 4.28 | 3.87 | 3.61 | 3.78 | 1.33 |
102.46 | 68.34 | 77.14 | 71.21 | 70.71 | 18.00 | ||
→4)-α-d-Quip3NAc-(1→ | C | 5.05 | 3.56 | 4.33 | 3.52 | 4.20 | 1.30 |
96.03 | 71.50 | 55.09 | 77.44 | 68.24 | 19.00 | ||
→4)-β-d-Galp-(1→ | D | 4.47 | 3.54 | 3.77 | 4.03 | 3.74 | 3.75 |
106.02 | 71.45 | 74.17 | 77.04 | 76.06 | 62.30 |
Chemical shifts for NAc were δH 2.02 and δC 23.7/175.6 for A and δH 1.97 and δC 23.2/175.4 for C.