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. 2013 Dec 5;15(2):261–269. doi: 10.1208/s12249-013-0054-y

Table III.

Theoretical Calculations of the %Increase in Thermal Mass on Fixing an Electrode Pair (with Guard Electrodes) to Different Volumes of Tubing Vial

Vial size mL Vial weight (mg) Electrode height mm Sensing electrode Top- and bottom-guard electrode 2 side-guard electrodes Total area of electrode assembly (mm2) Wt of electrode assembly Thermal mass as % of vial weight
Height (mm) Width (mm) Area (mm2) Height (mm) Width (mm) Area mm2 Height (mm) Width (mm) Area (mm2)
2 4,419 4.4 2.22 11 24.37 1.11 15.9 17.64 4.7 1.11 5.22 94.48 37.793 0.86
4 5,584 4.5 2.23 16.3 36.34 1.11 15.9 17.64 4.7 1.11 5.22 118.43 47.37 0.85
6 7,998 8.4 4.19 16.3 68.29 2.09 21.75 45.58 6.5 2.08 13.52 254.81 101.92 1.27
8 8,639 8.4 4.19 16.3 68.29 2.09 21.79 45.67 6.5 2.09 13.59 255.11 102.04 1.18
10 9,282 10 5 18 90 2.5 24 60 7 3 21 342.00 136.8 1.47

The application of electrodes was practicable by the current method (manually) for vial sizes 6, 8 and 10 mL as the dimensions of different electrode components were greater than 1 mm thickness. On contrary for smaller-sized glass vials, i.e. 2 and 4 mL, dimension electrodes and its spacing fractionate between 1 mm which may require an alternate methodology (sputtering) to apply thermal mass of the electrode