Table 1.
TCA Retention Times, Multiple Reaction Monitoring (MRM) Transition Ions, and Corresponding Collision Energies (CE)
| TCA | RT (min) | Quant ion (m/z) | CE (eV) | Qual ion (m/z) | CE (eV) |
|---|---|---|---|---|---|
| Amitriptyline | 6.2 | 278 > 233 | 17 | 278 > 91 | 25 |
| Amoxapine (ISTD) | 5.6 | 314 > 271 | 25 | ||
| Clomipramine | 7.7 | 315 > 86 | 17 | 315 > 58 | 38 |
| Cyclobenzaprine | 5.7 | 276 > 231 | 18 | 276 > 216 | 24 |
| Desipramine | 3.8 | 267 > 72 | 15 | 267 > 236 | 15 |
| Doxepin | 4.4 | 280 > 235 | 15 | 280 > 107 | 23 |
| Fluoxetine | 2.2 | 310 > 148 | 8 | 310 > 44 | 5 |
| Imipramine | 5.7 | 281 > 86 | 16 | 281 > 281 | 5 |
| Maprotiline | 3.8 | 278 > 250 | 20 | 278 > 219 | 24 |
| Mirtazapine | 7.2 | 266 > 195 | 25 | 266 > 72 | 20 |
| Norclomipramine | 4.7 | 301 > 72 | 6 | 301 > 301 | 18 |
| Nordoxepin | 2.9 | 266 > 235 | 15 | 266 > 107 | 23 |
| Norfluoxetine | 2.0 | 296 > 30 | 8 | 296 > 134 | 15 |
| Nortriptyline | 4.1 | 264 > 233 | 14 | 264 > 91 | 19 |
| Trazodone | 10.3 | 374 > 176 | 25 | 374 > 148 | 34 |
| Trimipramine | 6.2 | 295 > 100 | 19 | 295 > 58 | 35 |