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. 2014 Feb 25;136(10):3740–3743. doi: 10.1021/ja4128289

Figure 2.

Figure 2

Overlays of trajectory points for (a) a concerted [2,3]-rearrangement and (b) simple cleavage, with both occurring through the same transition state. The points are spaced at 10-fs intervals. Earlier points are darker and in back. The transition state is about one-third from the back.