Table 2.
Effects of t off in pulse deposition process on the compositions of (Bi,Sb) 2 - x Te 3 + x materials
Sb | Te | Bi | |
---|---|---|---|
Potentiostatic deposition process |
9.97 |
30.19 |
59.83 |
toff = 0.1 s |
7.09 |
31.29 |
61.63 |
toff = 0.4 s |
7.71 |
51.25 |
41.05 |
toff = 1 s |
12.02 |
69.43 |
18.54 |
toff = 1.6 s |
7.22 |
79.62 |
13.16 |
toff = 2 s |
5.77 |
84.06 |
10.17 |
toff = 4 s | 6.24 | 86.30 | 7.46 |
The electrolyte formula was 0.015 M Bi(NO3)3-5H2O, 0.005 M SbCl3, and 0.0075 M TeCl4; the bias voltage was set at -0.4 V; ton was set at 0.2 s; and toff was changed from 0.1 to 4 s.