Table 3.
Glyme | Dipole moment (D) at 25 °C | Dielectric Constant at 25 °C |
Solvatochromic polarity23 | Heat capacity at 25 °C (J mol−1 K−1) |
|
---|---|---|---|---|---|
ET(30), kcal mol−1 |
|||||
Monoglyme | 1.62,75 1.61,57 1.59,76 1.71 (in benzene)76 | 7.18,77 7.20,72 7.55,78 | 38.2 | 0.231 | 191.1479 |
Diglyme | 1.91,75 1.92,57, 76 1.87,45 1.97 (in benzene)76 | 7.480 | 38.6 | 0.244 | 277.76,79 276.9,45 279.0581 |
Triglyme | 2.16,57, 762.22 (in benzene)76 | 7.6252 | 38.9 | 0.253 | 367.78,79 367.3066 |
Tetraglyme | 2.44,762.4555, 76 | – | – | – | 457.1079 |