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. Author manuscript; available in PMC: 2015 Apr 9.
Published in final edited form as: Chem Rev. 2013 Nov 27;114(7):3369–3380. doi: 10.1021/cr4004715

Figure 11.

Figure 11

Hopping advantage maps for a two-step ET system (CuI → Int → RuIII) in each of three azurins. In each map the overall driving force −ΔG°(CuI → RuIII) is 0.7 eV, the reorganization energy (λ) is 0.8 eV, T is 298 K, the distance decay constant (β) is 1.1 Å−1, and the close-contact rate constant is (kET°) is 1013 s−1. τhop is the calculated hopping rate constant and τss is the calculated single-step rate constant. The first step driving forces (−ΔG° (Int → RuIII)) are indicated at the left. The contour lines are plotted at 0.1 log unit intervals. (Reprinted with permission from J. Am. Chem Soc2013135(30), 11151–11158. Copyright 2013 American Chemical Society.)