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Kinetics model of photoinduced electron transfer in Re(CO)3(dmp)(His124)|(Trp122)|Az. Light absorption produces electron (red) and hole (blue) separation in the MLCT-excited ReI complex. Migration of the hole to CuI via (W122)•+ is complete in less than 50 ns. Charge recombination proceeds on the microsecond time scale. (Reproduced from ref 152 with permission from AAAS.)
