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Reaction conditions: HetArBr (1.0 mmol), amine (1.2 mmol), LHMDS (2.2 mmol). Isolated yields are an average of two runs.
P4 (1 mol %), L4 (1 mol %), 50 °C.
P4 (2 mol %), L4 (2 mol %), 80 °C.
12 h.
Amine (1.4 mmol).
16 h.
P4 (4 mol %), L4 (4 mol %).
