TABLE 2.
Selected bond distances (Å) and angles (deg) for the two cationic units in the crystal structure of [Cu(I)-(trMCL-3)]PF6 •EtOH (16).
| 16 (I) | 16 (II) | |
|---|---|---|
| Cu(1)-S(1) | 2.2558(2) | 2.2729(3) |
| S(2)-Cu(1) | 2.2577(2) | 2.2576(2) |
| S(3)-Cu(1) | 2.3024(2) | 2.3339(2) |
| S(4)-Cu(1) | 2.3108(2) | 2.3088(3) |
| S(1)-Cu(1)-S(3) | 118.896(9) | 116.703(10) |
| S(1)-Cu(1)-S(4) | 110.019(9) | 104.482(9) |
| S(1)-Cu(1)-S(2) | 106.648(9) | 106.517(9) |
| S(2)-Cu(1)-S(3) | 106.772(9) | 109.358(9) |
| S(2)-Cu(1)-S(4) | 117.871(9) | 123.669(10) |
| S(3)-Cu(1)-S(4) | 97.026(8) | 96.580(9) |