Table 4.

Scope of the Catalytic, Asymmetric Borylation of α,β-Unsaturated Amides with Tetrakis(dimethylamino)diboron.

entry	product	yield (%)	enantiomeric ratio[a]
1	2a	91	93:7
2	2d	79	95:5
3	2h	68	92:8
4	2j	71	84:16
5	2k	72	70:30
6	2l	73	90:10
7	2m	62	76:24

^[a]Enantiomeric excess was determined by oxidation of 2 followed by SFC analysis of the corresponding alcohol.