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. 2014 Mar 30;2014:634194. doi: 10.1155/2014/634194

Table 1.

Acid dissociation constants (pKa) of ligands (20% (v/v) ethanol-water mixed, 25.0 ± 0.1°C, I = 0.1 mol/L by NaCl) (log10β is cumulative acid dissociation constants).

Ligand Species log10β pKa Values
2a LH3 11.37 ± 0.02 3.22 ± 0.01
LH2 20.03 ± 0.03 8.66 ± 0.02
LH 23.25 ± 0.03 11.37 ± 0.01

2b LH3 11.16 ± 0.04 3.24 ± 0.01
LH2 19.29 ± 0.05 8.13 ± 0.01
LH 22.53 ± 0.05 11.16 ± 0.03

2c LH3 11.08 ± 0.02 3.21 ± 0.02
LH2 19.23 ± 0.03 8.15 ± 0.01
LH 22.44 ± 0.03 11.08 ± 0.02

2d LH3 10.95 ± 0.08 3.74 ± 0.04
LH2 19.24 ± 0.09 8.29 ± 0.03
LH 22.98 ± 0.09 10.95 ± 0.05

2e LH3 11.12 ± 0.04 3.40 ± 0.02
LH2 19.67 ± 0.04 8.55 ± 0.02
LH 23.07 ± 0.05 11.12 ± 0.04

2f LH3 10.87 ± 0.05 3.50 ± 0.03
LH2 19.40 ± 0.07 8.53 ± 0.03
LH 22.90 ± 0.08 10.87 ± 0.01

2g LH4 12.70 ± 0.11 2.48 ± 0.07
LH3 20.88 ± 0.13 3.80 ± 0.05
LH2 24.68 ± 0.10 8.18 ± 0.06
LH 27.16 ± 0.09 12.70 ± 0.05