Table 3. Selected Angles (deg) for the Intermediates and Transition States of Pathways I and II.

	ORhBa	CγRhP1	CγRhH	CγRhB
Im0		162.12
TS1	123.19	160.83	108.48	109.05
Im1	175.60	176.78	99.32	92.03
TS2	176.11	168.01	82.40	91.34
Im2	173.12	162.02	66.29	91.95
TS3	166.68	171.08	56.05	91.37
Im3	172.82	176.68	45.88	89.26
TS4	129.25	161.06		44.33
TS5	132.52	169.61	52.87	97.80
Im5	95.17	164.57	46.09	101.96
TS6	98.27	171.07	37.80	52.50
TS7	130.77	154.08	62.24	43.96
TS8	114.65	164.48	101.04	110.60
Im8	97.03	170.96	90.69	104.76
TS9	101.70	175.15	90.45	85.69
Im9		175.80	90.92	57.81
TS10		174.02	45.19	56.81

^aO indicates the oxygen atom of the carbonyl moiety.