Table 2. Intramolecular AAC of Allylic Azides^a.

^aConditions: toluene, reflux, 2–8 h.

^bStarting azides exist as mixtures of terminal and internal azide stereoisomers; ratios noted indicate specific examples used in the experiment noted (¹H NMR).¹¹

^cRatio determined by NMR analysis of crude reaction mixtures.

^dThe relative stereochemistry of triazoles 27a, 28a, and 29a was determined by X-ray crystallography (Supporting Information).

^eInseparable mixtures.