Table 2. 13C NMR Data (100 MHz, in CD3OD) of 1–5 and 8, δ in ppm.
| no. | 1 | 2a | 2aa | 3 | 4 | 5 | 8 |
|---|---|---|---|---|---|---|---|
| 2 | 152.7, CH | 153.2, CH | 153.5, CH | 152.8, CH | 152.8, CH | 152.6, CH | 152.7, CH |
| 4 | 149.2, C | 149.5, C | 149.7, C | 149.1, C | 149.1, C | 148.9, C | 149.1, C |
| 5 | 118.3, C | 118.8, C | 118.5, C | 118.0, C | 118.1, C | 118.0, C | 118.0, C |
| 6 | 156.0, C | 156.5, C | 156.5, C | 155.9, C | 156.0, C | 155.8, C | 156.0, C |
| 8 | 139.2, CH | 140.7, CH | 138.9, CH | 139.0, CH | 139.5, CH | 141.0, CH | 139.5, CH |
| 1′ | 89.6, CH | 87.2, CH | 86.8, CH | 88.0, CH | 87.1, CH | 87.7, CH | 87.3, CH |
| 2′ | 81.0, CH | 90.8, CH | 89.7, CH | 89.5, CH | 90.3, CH | 90.8, CH | 90.3, CH |
| 3′ | 76.4, CH | 73.0, CH | 72.7, CH | 72.5, CH | 73.1, CH | 72.4, CH | 73.2, CH |
| 4′ | 77.5, CH | 77.8, CH | 77.5, CH | 78.4, CH | 77.7, CH | 78.3, CH | 77.5, CH |
| 5′ | 25.3, CH2 | 26.4, CH2 | 25.5, CH2 | 25.0, CH2 | 25.1, CH2 | 25.0, CH2 | 25.2, CH2 |
| 6′ | 65.2, CH | 66.3, CH | 57.9, CH | 69.6, CH | 65.1, CH | 64.1, CH | 65.2, CH |
| 7′ | 91.8, C | 94.5, C | 94.1, C | 94.2, C | 92.0, C | 93.3, C | 91.9, C |
| 8′ | 70.5, CH | 92.6, C | 200.5, C | 68.4, CH | 70.5, CH | 69.9, CH | 70.5, CH |
| 9′ | 69.0, CH | 38.4, CH2 | 40.6, CH2 | 70.7, CH | 69.2, CH | 73.0, CH | 69.1, CH |
| 10′ | 76.9, CH | 71.0, CH | 74.6, CH | 79.0, CH | 76.9, CH | 76.6, CH | 76.9, CH |
| 11′ | 169.8, C | 172.3, C | 170.9, C | 169.9, C | 170.0, C | 170.4, C | 169.8, C |
| 1″ | 165.8, C | 164.7, C | 165.7, C | ||||
| 2″ | 129.6, C | 131.1, C | 127.0, C | ||||
| 3″ | 140.4, CH | 144.3, CH | 140.3, CH | ||||
| 4″ | 13.6, CH3 | 13.7, CH3 | 13.7, CH3 | ||||
| 5″ | 10.9, CH3 | 54.9, CH2 | 10.9, CH3 | ||||
| 2′-OCH3 | 57.9 | 58.0 | 57.1 | 56.9 | 57.0 | 56.9 | |
| 11′-OCH3 | 51.3 | 51.7 | 52.7 | 51.4 | 51.4 | 50.9 | 51.3 |
Measured in DMSO-d6.