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. 2014 Feb 20;53(5):2370–2380. doi: 10.1021/ic4013137

Table 1. Times for Exchange of Hydride Ligands between Isotopologues, And for Exchange of Hydride with 1 atm of H2/D2 Gas, Giving Qualitative Times to Reach Equilibriuma.

compound isotopologue exchange gas exchange
[LtBuFe(μ-H)]2 (1) <45 min 2 d
[LMeFe(μ-H)]2 (3) 2 h <1 min
[LtBuCo(μ-H)]2 none  
a

Each solution was shaken for the duration of the experiment.