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. 2014 Apr 24;4:4775. doi: 10.1038/srep04775

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(a) Gd@C₈₂(OH)₂₂ has a favorable contact with MMP-2 specifically at both the ligand specificity S1′ loop and Zn²⁺-coordinated active site. (b) C₈₂(OH)₂₂ contacts are reduced in both the S1′ and the active site of MMP-2, while interactions with upper rim residues largely remain.