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. 2014 Mar 31;16(8):2122–2125. doi: 10.1021/ol5005438

Figure 2.

Figure 2

13C NMR analyses of OvoA reactions. (A) Formation of compound 4 and cysteine sulfinic acid 8 when hercynine and cysteine were the substrates. (B) Oxidation of cysteine to cystine in reaction A after all hercynine was consumed. (C) Formation of cystine (9) when cysteine was the only substrate. (D) Formation of compound 6 and cysteine sulfinic acid (8) when histidine and cysteine were the substrates.