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. 2014 Feb 3;33(4):858–867. doi: 10.1021/om400752a

Figure 2.

Figure 2

Structure of the symmetrical isomer of Fe(pdt)(CO)2(dppv) (1c). Thermal ellipsoids are set at the 50% probability level. Hydrogen atoms are omitted for clarity. Key distances (Å) and angles (deg): Fe1–C1, 1.808(2); Fe1–C2, 1.799(2); Fe1–P2, 2.2204(1); Fe1–P1, 2.214(1); Fe1–S1, 2.3441(6); Fe1–S2, 2.3462(6); C1–Fe1–C2, 169.3(1); C1–Fe1–P2, 91.10(7); C2–Fe1–P2, 95.25(7); C1–Fe1–P1, 93.85(7); C2–Fe1–P1, 91.80(7); P2–Fe1–P1, 86.76(2); C1–Fe1–S1, 87.82(7); C2–Fe1–S1, 82.97(7); P2–Fe1–S1, 177.54(2); P1–Fe1–S1, 91.58(2); C1–Fe1–S2, 83.20(7); C2–Fe1–S2, 91.74(6); P2–Fe1–S2, 89.50(2); P1–Fe1–S2, 175.07(2); S1–Fe1–S2, 92.25(2).