Figure 4.

X-ray diffractograms of GOE-PAS_n in the pristine state at room temperature (black), at 80 °C (blue, Iso for GOE-PAS₂₀ and Col_h for GOE-PAS_50/100), and at 120 °C (red, Iso for GOE-PAS_50/100). Patterns with offset (below), expansion of WAXS range (above); (a) SAXS pattern in the pristine state at room temperature (top, left, black), where the reflections 1, 2, 3, and 4 are lamellar orders; (b,c) (10), (11), and (20) are the reflections of the bidimensional hexagonal lattice; h_ch and h_GlA are diffuse scatterings due to lateral distances between aliphatic chains and, presumably, to periodicities along the polymer core.